全文获取类型
收费全文 | 962篇 |
免费 | 107篇 |
国内免费 | 135篇 |
专业分类
安全科学 | 69篇 |
废物处理 | 10篇 |
环保管理 | 150篇 |
综合类 | 515篇 |
基础理论 | 185篇 |
污染及防治 | 77篇 |
评价与监测 | 168篇 |
社会与环境 | 12篇 |
灾害及防治 | 18篇 |
出版年
2024年 | 4篇 |
2023年 | 31篇 |
2022年 | 42篇 |
2021年 | 36篇 |
2020年 | 37篇 |
2019年 | 24篇 |
2018年 | 19篇 |
2017年 | 30篇 |
2016年 | 35篇 |
2015年 | 32篇 |
2014年 | 34篇 |
2013年 | 51篇 |
2012年 | 49篇 |
2011年 | 54篇 |
2010年 | 41篇 |
2009年 | 45篇 |
2008年 | 35篇 |
2007年 | 48篇 |
2006年 | 55篇 |
2005年 | 32篇 |
2004年 | 30篇 |
2003年 | 45篇 |
2002年 | 24篇 |
2001年 | 23篇 |
2000年 | 31篇 |
1999年 | 30篇 |
1998年 | 24篇 |
1997年 | 16篇 |
1996年 | 15篇 |
1995年 | 23篇 |
1994年 | 33篇 |
1993年 | 18篇 |
1992年 | 21篇 |
1991年 | 19篇 |
1990年 | 13篇 |
1989年 | 17篇 |
1988年 | 23篇 |
1987年 | 18篇 |
1986年 | 8篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1983年 | 9篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1980年 | 4篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1975年 | 1篇 |
1974年 | 2篇 |
排序方式: 共有1204条查询结果,搜索用时 15 毫秒
1.
全(多)氟烷基化合物(per(poly)fluoroalkyl substances,PFASs)在环境各个介质及人体样品中广泛被检出,近年,在室内空气和灰尘中也普遍发现PFASs.研究表明,室内空气中PFASs的含量普遍高于室外空气,室内空气和灰尘中的PFASs可能是室外空气的污染来源及人体暴露源,因此室内环境中PFASs成为环境领域的又一个研究热点.但目前为止,我国还没有开展室内空气中PFASs的相关研究,室内灰尘中PFASs的研究也相对较少.本文就室内空气和灰尘中PFASs的采样与分析方法、污染现状、来源分析及人体暴露等4个方面进行了综合阐述,以期为我国室内环境中PFASs的研究提供参考. 相似文献
2.
Chou CJ 《Environmental monitoring and assessment》2006,119(1-3):571-598
Statistical analyses were applied at the Hanford Site, USA, to assess groundwater contamination problems that included (1) determining local backgrounds to ascertain whether a facility is affecting the groundwater quality and (2) determining a ‘pre-Hanford' groundwater background to allow formulation of background-based cleanup standards. The primary purpose of this paper is to extend the random effects models for (1) assessing the spatial, temporal, and analytical variability of groundwater background measurements; (2) demonstrating that the usual variance estimate s
2, which ignores the variance components, is a biased estimator; (3) providing formulas for calculating the amount of bias; and (4) recommending monitoring strategies to reduce the uncertainty in estimating the average background concentrations. A case study is provided. Results indicate that (1) without considering spatial and temporal variability, there is a high probability of false positives, resulting in unnecessary remediation and/or monitoring expenses; (2) the most effective way to reduce the uncertainty in estimating the average background, and enhance the power of the statistical tests in general, is to increase the number of background wells; and (3) background for a specific constituent should be considered as a statistical distribution, not as a single value or threshold. The methods and the related analysis of variance tables discussed in this paper can be used as diagnostic tools in documenting the extent of inherent spatial and/or temporal variation and to help select an appropriate statistical method for testing purposes. 相似文献
3.
4.
A directional passive air sampler for monitoring polycyclic aromatic hydrocarbons (PAHs) in air mass
Tao S Liu YN Lang C Wang WT Yuan HS Zhang DY Qiu WX Liu JM Liu ZG Liu SZ Yi R Ji M Liu XX 《Environmental pollution (Barking, Essex : 1987)》2008,156(2):435-441
A passive air sampler was developed for collecting polycyclic aromatic hydrocarbons (PAHs) in air mass from various directions. The airflow velocity within the sampler was assessed for its responses to ambient wind speed and direction. The sampler was examined for trapped particles, evaluated quantitatively for influence of airflow velocity and temperature on PAH uptake, examined for PAH uptake kinetics, calibrated against active sampling, and finally tested in the field. The airflow volume passing the sampler was linearly proportional to ambient wind speed and sensitive to wind direction. The uptake rate for an individual PAH was a function of airflow velocity, temperature and the octanol-air partitioning coefficient of the PAH. For all PAHs with more than two rings, the passive sampler operated in a linear uptake phase for three weeks. Different PAH concentrations were obtained in air masses from different directions in the field test. 相似文献
5.
Toscas PJ 《Environmental monitoring and assessment》2008,137(1-3):379-385
Ammonia is an important water quality variable, which in excess, can be detrimental to waterways and their ecosystems. In
the Ecosystem Health Monitoring Program in South-east Queensland ammonia is monitored monthly, however, often more than 50%
of the ammonia observations in Moreton Bay are below detection limit, making it difficult to draw useful inferences. In this
paper a clipped Gaussian random field is used to spatially model and map the probability of detectable concentration of ammonia.
The methodology is applied to the Moreton Bay samples collected in February 2005. The results suggest that for this month
the oceanic impacted areas have higher probability of detectable ammonia concentration than the areas closer to the main sources
of anthropogenic inputs. 相似文献
6.
7.
水质监测频率与极端气候对高原湖泊入湖河流氮磷通量估算的影响 总被引:1,自引:0,他引:1
河流是流域氮磷营养盐的主要输出途径之一,准确掌握其通量变化和驱动因素对流域营养盐管理具有重要意义.本研究以滇池主要入湖河流宝象河为例,基于周水质观测数据和逐日水量数据,构建了河流氮磷通量LOADSET模型.估算了宝象河不同时间尺度(日、季、年)TN和TP的通量,评估了4种低频水质采样和极端气候指数对河流氮磷通量计算的影响.结果表明:①2018年宝象河的TN和TP年通量分别为270.49 t和11.19 t,存在显著的年内差异,夏季是通量最高的季节,分别占TN和TP年通量的40.78%和41.96%.②基于LOADEST模型的低频水质采样的氮磷估算结果与高频采样差异较小,宝象河TN、TP通量估算受采样频率影响较小.③宝象河的TN和TP通量变化受连续5日最大降水量、平均最低气温、平均最高气温、最低气温、最低气温极大值、最高气温极小值和平均温差7种极端气候指数的显著影响. 相似文献
8.
基于RF-LSTM的鸡舍恶臭气体预测研究 总被引:1,自引:0,他引:1
以鸡舍氨气为研究对象,对鸡舍氨气预测模型进行了研究.首先,利用随机森林算法(RF)对影响鸡舍氨气浓度的环境变量进行重要性排序,选取温度、湿度、光照、气象温度、降雨量作为模型的输入变量;在此基础上,构建了基于长短时记忆神经网络(LSTM)的鸡舍氨气浓度预测模型,并将提出的预测模型应用于江苏省宜兴市某养鸡场的氨气浓度预测中,并与LSTM模型、RF-Elman模型和RF-BP模型进行了对比实验,结果表明,基于RF-LSTM模型的预测效果最好,其平均绝对误差(MAE)、平均绝对百分误差(MAPE)和均方根误差(RMSE)分别为0.9183、4.9637%和1.4262;同时,为了验证该模型的性能,本文还实现了不同时间尺度的鸡舍氨气浓度预测,提前2h、3h、4h、5h氨气预测的平均绝对误差(MAE)分别为1.6218、2.1991、2.8553和3.0677.本文提出的预测模型提高了鸡舍氨气浓度的预测精度,可为减少鸡舍恶臭气体排放提供科学依据. 相似文献
9.
The distribution and sources of organochlorine pesticides (OCPs) in air and surface waters were monitored in Nairobi City using triolein-filled semipermeable membrane devices (SPMDs). The SPMDs were extracted by dialysis using n-hexane, followed by cleanup by adsorption chromatography on silica gel cartridges. Sample analysis was done by GC-ECD and confirmed by GC–MS. Separation of means was achieved by analysis of variance, followed by pair-wise comparison using the t-test (p≤ 0.05). The total OCPs ranged between 0.018 – 1.277 ng/m3 in the air and <LOD – 1391.000 ng/m3 in surface waters. Based on the results, the means of Industrial Area, Dandora and Kibera were not significantly different (p≤ 0.05), but were higher (p≤ 0.05) than those of City square and Ngong’ Forest. The results revealed non-significant (p≤ 0.05) contribution of long-range transport to OCP pollution in Nairobi City. This indicated possible presence of point sources of environmental OCPs in the city. The water-air fugacity ratios indicated that volatilization and deposition played an important role in the spatial distribution of OCPs in Nairobi City. This indicated that contaminated surface waters could be major sources of human exposure to OCPs, through volatilization. The incremental lifetime cancer risks (ILCR) determined from inhalation of atmospheric OCPs were 2.3745 × 10?13 – 1.6845 × 10?11 (adult) and 5.5404 × 10?13 – 3.9306 × 10?11 (child) in the order: Dandora > Kibera > Industrial Area > City Square > Ngong’ Forest. However, these were lower than the USEPA acceptable risks, 10?6 – 10?4. This study concluded that atmospheric OCPs did not pose significant cancer risks to the residents. 相似文献
10.